团队带头人—张羊换

个人综合简介：张羊换，男，1956年3月出生，博士，二级教授，博士生导师。长期从事贮氢材料的研究与应用开发。近年来，主持和完成包括“国家863”项目、国家自然科学基金、工业和信息化部专项基金等项目十余项。在国际著名期刊上发表第一作者SCI收录论文200余篇，总引用次数2000余次。获授权发明专利10项，出版贮氢材料英文专著两部，参与出版英文专著（其中的部分章节）两部。获内蒙古自治区自然科学二等奖2项。应邀成为国际电化学学会会员(IES)，国际期刊“Int. J. Hydrogen Energy”、“J. Alloys Compd”和“J. Power Sources”等十余家国际著名期刊的特约审稿人。参加在美国、日本、德国、韩国等国家举行的国际贮氢材料会议10余次，并作特邀学术报告。2008年入选美国“Who’s Who in the World”，同年入选英国“2000 Outstanding Scientists”；2011年被美国传记研究院授予“2011年度杰出科学奖”；2013年入选国际Eni Award候选人。

教育背景：1982年大连理工大学金属材料及热处理专业毕业，获学士学位；1990年东北大学金属材料专业毕业，获硕士学位；2004年钢铁研究总院材料学专业毕业，获博士学位。

工作经历：1985年-1992年，包头钢铁学院冶金系材料学专业

1992年-2011年，内蒙古科技大学材料与冶金学院材料学专业

2011年至今，内蒙古科技大学，内蒙古自治区白云鄂博矿多金属资源综合利用重点实验室

研究领域：稀土贮氢材料。在国内最早把真空快淬技术应用到贮氢材料的制备中，并成功制备出无钴AB₅型贮氢合金以及高容量长寿命RE−Mg−Ni系贮氢合金，性能达到国际先进水平。经过多年的努力，发现用氦气作保护气可有效抑制含镁贮氢合金在感应熔炼过程中的镁挥发问题，从根本上解决了这一技术难题。用真空快淬技术制备出具有非晶、纳米晶结构的Mg₂Ni-型贮氢合金，合金的低温吸放氢性能良好，成果受到国内外贮氢领域的高度关注。最近几年，致力于车载燃料电池用Mg基贮氢材料的研究与开发，取得了重要进展。开发的新型贮氢材料应用到风能、太阳能等间歇性能源系统中，实现了能量输出的稳定性。

奖励与荣誉

1. 燃料电池用快淬纳米晶/非晶RE-Mg基合金的气态吸放氢动力学及机理研究，内蒙古自治区人民政府，内蒙古自治区自然科学三等奖，2017年，排名第一

2. 快淬高容量新型La-Mg-Ni系贮氢合金循环稳定性研究，内蒙古自治区人民政府，内蒙古自治区自然科学二等奖，2012年，排名第一

3. 特种工艺制备低成本、高性能稀土系无钴AB5型贮氢合金，内蒙古自治区人民政府，内蒙古自治区自然科学二等奖，2009年，排名第一

   科学研究项目

   1）国家863计划课题“特种工艺制备燃料电池用高容量纳米晶/非晶镁基复合储氢材料(2006AA05Z132)”，2006.12-2008.12

   2）国家自然科学基金“快淬非晶态A₂B型Mg基电极合金的晶化过程与电化学循环稳定性的关联研究(50871050)”，2009.01-2011.12

   3）国家863重大专项课题“稀土新型储氢材料关键制备技术与应用开发（2011AA03A408）”，2011.01-2013.12

   4）国家自然科学基金“不同凝固条件下稀土镁基AB₂型贮氢合金多相复合效应研究(51161015)”，2012.01-2015.12

   5）国家自然科学基金“多元稀土及金属硫化物掺杂快淬-球磨纳米晶/非晶镁基贮氢合金超细颗粒的吸放氢动力学及机理研究(51371094)”，2014.01-2017.12

   6）国家自然科学基金“稀土及晶体缺陷密度与TiFe系合金活化及吸放氢动力学的关联及机理研究(51761032)”，2018.01-2021.12

   7）国家自然科学基金“石墨烯催化稀土—镁—铝基复合储氢材料动力学及热力学研究(51871125)”，2019.01-2022.12

   8）内蒙古自治区自然科学基金重大项目“燃料电池用快淬纳米晶/非晶RE-Mg基合金的气态吸放氢动力学及机理研究（2011ZD10）”，2011.01-2013.12

   代表性学术成果(100篇)

   [1]Yang-huan Zhang, Mei-yan Chen, Xin-lin Wang, Guo-qing Wang, Xiao-ping Dong, Yan Qi, Microstructure and electrochemical characteristics of Mm(Ni,Co,Mn,Al)₅Bx (x = 0–0.4) hydrogen storage alloys prepared by cast and rapid quenching,Electrochimica Acta49 (2004) 1161–1168

   [2]Yang-Huan Zhang, Ping Li, Xin-Lin Wang, Yu-Fang Lin, Guo-qing Wang.The effects of rapid quenching on the electrochemical characteristics and microstructures of AB₂Laves phase electrode alloys,Journal of Power Sources128 (2004) 90–96

   [3] Yang-huan Zhang, Mei-yan Chenb, Xin-lin Wang, Guo-qing Wang, Yu-fang Lin, Yan Qi, Effect of boron additive on the cycle life of low-Co AB5-type electrode consisting of alloy prepared by cast and rapid quenching,Journal of Power Sources125 (2004) 273–279

   [4]Yang-Huan Zhang, Guo-Qing Wang, Xiao-Ping Dong, Shi-Hai Guo, Jian-Min Wu, Xin-Lin Wang,Investigation on the microstructure and electrochemical performances of La₂Mg(Ni_0.85Co_0.15)₉B_x(x=0-0.2) hydrogen storage electrode alloys prepared by casting and rapid quenching,Journal of Alloys and Compounds379 (2004) 298–304

   [5] Yang-Huan Zhang, Mei-yan Chen, Xiao-ping Dong, Guo-qing Wang, Xin-lin Wang,The effects of rapid quenching on the microstructures and electrochemical properties of low-Co AB₅-type electrode alloy,Journal of Alloys and Compounds376 (2004) 275–281

   [6]Yang-huan Zhang, Mei-yan Chen, Xin-lin Wang, Guo-qing Wang, Yu-fang Lin, Yan Qi,Effect of boron addition on the microstructures and electrochemical properties of MmNi_3.8Co_0.4Mn_0.6Al_0.2electrode alloys prepared by casting and rapid quenching,Journal of Alloys and Compounds373 (2004) 291–297

   [7]Yang-Huan Zhang, Ping Li, Xin-Lin Wang, Yu-Fang Lin, Xuan-Hui Qu,Electrochemical characteristics and microstructures of rapidly quenched Ti_0.5Zr_0.2Mn_0.2Cr_0.5V_0.2Ni_0.95alloy,Journal of Alloys and Compounds364 (2004) 289–294

   [8] Yang-huan Zhang, Guo-qing Wang, Xiao-ping Dong, Shi-hai Guo, Xin-lin Wang,Effect of rapid quenching on the electrochemical performances and microstructures of the Mm(NiMnSiAl)_4.3Co0.6-xFe_x(x=0-0.6) electrode alloys,Journal of Power Sources137 (2004) 309–316

   [9]Yang-huan Zhang, Xiao-ping Dong, Shi-hai Guo, Guo-qing Wang, Jiang-yuan Ren, Xin-lin Wang,The cycle stabilities of the as-cast and quenched La₂Mg(Ni_0.85Co_0.15)₉M_x(M=B, Cr, Ti; x = 0, 0.1) hydrogen storage alloys,Journal of Alloys and Compounds398 (2005) 178–183

[10]Yang-Huan Zhang, Guo-Qing Wang, Xiao-Ping Dong, Shi-Hai Guo, Jiang-Yuan Ren, Xin-Lin Wang,Effect of substituting Co with Fe on the cycle stabilities of the as-cast and quenched AB₅-type hydrogen storage alloys,Journal of Power Sources148 (2005) 105–111

[11] Yang-huan Zhang, Xiao-ping Dong, Guo-qing Wang, Shi-hai Guo, Xin-lin Wang,Effect of substituting Mm with La on the electrochemical performances of Co-free La_xMm_1-x(NiMnSiAlFe)_4.9(x = 0-1) electrode alloys prepared by casting and rapid quenching,Journal of Power Sources140 (2005) 381–387

[12] Yang-huan Zhang, Guo-qingWang, Xiao-ping Dong, Shi-hai Guo, Xin-linWang,Effect of rapid quenching on the microstructures and electrochemical performances of Co-free AB₅-typehydrogen storage alloys,International Journal of Hydrogen Energy30 (2005) 1091 – 1098

[13] Yang-Huan Zhang, Xiao-Ping Dong, Guo-Qing Wang, Shi-Hai Guo, Xin-Lin Wang,Microstructures and electrochemical performances of La₂Mg(Ni_0.85Co_0.15)₉Cr_x(x = 0～0.2) electrode alloys prepared by casting and rapid quenching,Journal of Power Sources144 (2005) 255–261

[14] Yang-Huan Zhang, Xiao-Ping Dong, Shi-Hai Guo, Guo-QingWang, Jiang-Yuan Ren, Xin-LinWang,Microstructures and electrochemical performances of La₂Mg(Ni_0.85Co_0.15)₉M_x(M=B, Cr, Ti; x = 0, 0.1) electrode alloys prepared by casting and rapid quenching,International Journal of Hydrogen Energy31 (2006) 63–69

[15]Yang-huan Zhang, Xiao-ping Dong, Guo-qing Wang, Shihai Guo, Jiang-yuan Ren, Xin-lin Wang,Effect of boron addition on the microstructures and electrochemical performances of La₂Mg(Ni_0.85Co_0.15)₉hydrogen storage alloy,Materials Science and Engineering A416 (2006) 219–225

[16]Yang-Huan Zhang, Xiao-Ping Dong, Guo-Qing Wang, Shi-Hai Guo, Jiang-Yuan Ren, Xin-Lin Wang,Microstructure and electrochemical performances of La_0.7Mg_0.3Ni_2.55-xCo_0.45Cu_x(x=0-0.4) hydrogen storage alloys prepared by casting and rapid quenching,Journal of Alloys and Compounds417 (2006) 224–229

[17]Yang-Huan Zhang, Xiao-Ping Dong, Guo-QingWang, Shi-Hai Guo, Jiang-Yuan Ren, Xin-Lin Wang,Effect of boron additive on electrochemical cycling life of La-Mg-Ni alloys prepared by casting and rapid quenching,International Journal of Hydrogen Energy32 (2007) 594–599

[18] Yang-huan Zhang, Bao-wei Li, Hui-ping Ren, Ying Cai, Xiao-ping Dong, Xin-lin Wang,Effects of Cr addition on the microstructures and electrochemical properties of as-cast and quenched La₂Mg(Ni_0.85Co_0.15)₉electrode alloys,Journal of Alloys and Compounds436 (2007) 209–215

[19]Yang-huan Zhang, Hui-ping Ren, Bao-wei Li, Xiao-ping Dong, Ying Cai, Xin-lin Wang,Effect of rapid quenching on the microstructures and electrochemical characteristics of La_0.7Mg_0.3Ni_2.55−xCo_0.45Al_x(x=0–0.4) electrode alloys,Materials Characterization58 (2007) 637–644

[20] Yang-Huan Zhang, Bao-Wei Li, Ying Cai, Xiao-Ping Dong,Jiang-Yuan Rena, Xin-Lin Wang,Microstructure and electrochemical performances of La_0.7Mg_0.3Ni_2.55−xCo_0.45M_x(M = Cu, Cr, Al;x= 0–0.4) hydrogen storage alloys prepared by casting and rapid quenching,Materials Science and Engineering A458 (2007) 67–72

[21]Yang-Huan Zhang, Bao-Wei Li, Hui-Ping Ren, Zhang-WangWu, Yin Cai, Xin-LinWang,Effects of substituting Ni with Al on the microstructure and electrochemical performances of the as-cast and quenched La-Mg-Ni-based (PuNi₃-type) hydrogen storage alloys,Materials Chemistry and Physics105 (2007) 86–91

[22]Yang-huan Zhang, Dong-liang Zhaoa, Xiao-ying Han, Bao-wei Li, Xiao-ping Dong, Xin-linWang,Electrochemical characteristics of mechanical alloyed(Mg_1−xZrx)₂Ni(x=0.0.1)electrode alloys,International Journal of Hydrogen Energy32 (2007) 2830–2835

[23]Yang-huan Zhang, Dong-liang Zhao, Hui-ping Ren, Zhong-wang Wu, Xiao-ping Dong and Xin-lin Wang,Investigation on the microstructure and electrochemical performances of as-cast and quenched La_0.7Mg_0.3Co_0.45Ni_2.55−xM_x(M=Cu, Al, Mn;x=0–0.4) electrode alloys,Journal of Alloys and Compounds446–447 (2007) 643–647

[24]Yang-huan Zhang, Bao-wei Li, Hui-ping Ren, Ying Cai, Xiao-ping Dong, Xin-lin Wang,Effects of substituting Ni with Cu on the microstructures and electrochemical characteristics of the as-cast and quenched La_0.7Mg_0.3Ni_2.55-xCo_0.45Cu_x(x = 0-0.4) electrode alloys,International Journal of Hydrogen Energy32 (2007) 3420 – 3426

[25]Yang-huan Zhang, Bao-wei Li , Hui-ping Ren , Ying Cai, Xiao-ping Dong, Xin-lin Wang, Investigation on structures and electrochemical performances of the as-cast and quenched La_0.7Mg_0.3Co_0.45Ni_2.55-xFe_x(x = 0-0.4) electrode alloys,International Journal of Hydrogen Energy32 (2007) 4627 – 4634

[26]Yanghuan Zhang, Dongliang Zhao,Baowei Li,Huiping Ren , Shihai Guo, Xinlin Wang, Effects of the substitution of Al for Ni onthe structure and electrochemical performanceof La_0.7Mg_0.3Ni_2.55-xCo_0.45Al_x(x = 0-0.4) electrode alloys,Journal of Materials Science42(19)(2007)8172-8177

[27] Yang-huan Zhang, Xiao-ying Han, Bao-wei Li, Hui-ping Ren, Xiao-ping Dong, Xin-lin Wang, Electrochemical characteristics of Mg_2-xZr_xNi(x = 0 - 0.6)electrode alloys prepared by mechanical alloying,Journal of Alloys and Compounds450 (2008) 208–214

[28]Yang-huan Zhang, Xiao-ying Han, Bao-wei Li, Hui-ping Ren, Xiao-ping Dong, Xin-lin Wang, Effects of substituting Mg with Zr on the electrochemical characteristics of Mg₂Ni-type electrode alloys prepared by mechanical alloying,Materials Characterization59(2008)390-396

[29]Yang-huanZhang, Dong-liangZhao, Bao-wei Li, Xiao-long Zhao, Zhong-wangWu, Xin-lin Wang,Microstructures and electrochemical characteristics of the La_0.75Mg_0.25Ni_2.5M_x(M=Ni, Co; x = 0-1.0) hydrogen storage alloys,International Journal of Hydrogen Energy33 (2008) 1868 – 1875

[30]Yang-Huan Zhang, Bao-Wei Li, Hui-Ping Ren, Ying Cai, Xiao-Ping Dong, Xin-Lin Wang,Cycle stabilities of the La_0.7Mg_0.3Ni_2.55−xCo_0.45M_x(M = Fe, Mn, Al;x= 0, 0.1) electrode alloys prepared by casting and rapid quenching,Journal of Alloys and Compounds458 (2008) 340–345

[31]Yang-Huan Zhang, Bao-Wei Li, Hui-Ping Ren, Zhong-Wang Wu, Xiao-Ping Dong, Xin-Lin Wang,Influences of the substitution of Fe for Ni on structures and electrochemical performances of the as-cast and quenched La_0.7Mg_0.3Co_0.45Ni_2.55-xFe_x(x = 0-0.4) electrode alloys,Journal of Alloys and Compounds460 (2008) 414–420

[32]Yang-huan Zhanga, Bao-wei Li, Hui-ping Ren, Zhong-wang Wu, Xiao-ping Dongb, and Xin-lin Wang, Investigation on structures and electrochemical characteristics of the as-cast and quenched La_0.5Ce_0.2Mg_0.3Co_0.4Ni_2.6−xMn_x(x=0–0.4) electrode alloys,Journal of Alloys and Compounds461 (2008) 591–597

[33]Yang-huan Zhang, Xiao-ping Dong, Bao-wei Li, Hui-ping Ren, Zhong-wang Wu, Xin-lin Wang,Microstructures and electrochemical performances of La_0.75Mg_0.25Ni_3.5M_x(M = Ni, Co; x = 0-0.6) hydrogen storage alloys,Journal of Alloys and Compounds465(2008)422-428

[34]Yang-huan Zhang, Bao-wei Li, Hui-ping Ren, Shi-hai Guo, Zhong-wangWu, Xin-linWang, An investigation on the hydrogen storage characteristics of the melt-spun nanocrystalline and amorphous Mg_20−xLa_xNi₁₀(x= 0, 2) hydrogen storage alloys,Materials Chemistry and Physics115 (2009) 328–333

[35]Yang-huan Zhang, Bao-wei Li, Hui-ping Ren, Shi-hai Guo, Zhong-wang Wu, Xin-lin Wang,Hydriding and dehydriding characteristics of nanocrystalline and amorphous Mg₂₀Ni_10-xCo_x(x=0–4) alloys prepared by melt-spinning,International Journal of Hydrogen Energy34( 2009)2684 – 2691

[36]Yang-huan Zhang, Bao-wei Li, Hui-ping Ren, Zai-guang Pang, Shi-hai Guo, Xin-lin Wang, An electrochemical investigation of melt-spun nanocrystalline and amorphous Mg₂Ni-type electrode alloys,Journal of Alloys and Compounds477(2009) 759–763

[37]Yang-huan Zhang, Dong-liang Zhao, Shi-hai Guo, Yan Qi, Zhong-wangWu, Xin-linWang, The hydrogenation and dehydrogenation behaviours of Mg_20−xLa_xNi₁₀(x= 0–6) alloys prepared by casting and rapid quenching,Journal of Alloys and Compounds476(2009)475-461

[38]Yang-huan Zhang, Bao-wei Li, Hui-ping Ren, Shi-hai Guo, Qi Yan, Xin-linWang, Investigation on the structures and electrochemical performances of La_0.75−xZr_xMg_0.25Ni_3.2Co_0.2Al_0.1(x= 0–0.2) electrode alloys prepared by melt spinning,Journal of Alloys and Compounds480(2009)547-553

[39]Yang-huan Zhang, Hui-ping Ren, Shi-hai Guo, Zai-guang Pang, Yan Qi, Xin-lin Wang, Electrochemical hydrogen storage characteristics of nanocrystalline and amorphous Mg₂₀Ni_10−xCo_x(x= 0–4) alloys prepared by melt spinning,Journal of Alloys and Compounds480 (2009) 750–755

[40]Yang-huan Zhang, Hui-ping Ren, Bao-wei Li, Shi-hai Guo, Qing-chun Wang, Xin-lin Wang, Structures and electrochemical hydrogen storage behaviours of La_0.75-xPr_xMg_0.25Ni_3.2Co_0.2A_0.1(x = 0–0.4) alloys prepared by melt spinning,International Journal of Hydrogen Energy34(2009)6335–6342

[41]Yang-huan Zhang, Hui-ping Ren, Bao-wei Li, Shi-hai Guo,Zai-guang Pang, Xin-lin Wang,Electrochemical hydrogen storage characteristics of nanocrystalline and amorphous Mg₂₀Ni_10-xCo_x(x=0-4) alloys prepared by melt spinning,International Journal of Hydrogen Energy34(2009)8144– 8151

[42]Yang-huan Zhang, Bao-wei Li, Hui-ping Ren, Shi-hai Guo, Qi Yan, Xin-linWang, Structures and electrochemical cycle stability of La_0.75−xPr_xMg_0.25Ni_3.2Co_0.2Al_0.1(x= 0–0.4) alloys prepared by melt spinning,Materials Chemistry and Physics118 (2009) 129–134

[43]Yang-huan Zhang, Bao-wei Li, Hui-ping Ren, Shi-hai Guo, Qi Yanand Xin-lin Wang,Structures and electrochemical hydrogen storage characteristics of La_0.75−xPr_xMg_0.25Ni_3.2Co_0.2Al_0.1(x= 0–0.4) alloys prepared by melt spinning,Journal of Alloys and Compounds485 (2009) 333–339

[44]Yang-huan Zhang, Dong-liang Zhao, Bao-wei Li, Hui-ping Ren, Shi-hai Guo, Xin-lin Wang,Electrochemical hydrogen storage characteristics of nanocrystalline Mg₂₀Ni_10−xCu_x(x=0–4) alloys prepared by melt-spinning,Journal of Alloys and Compounds491 (2010) 589–594

[45]Yang-huan Zhang, Zhuo-cheng Liu, Bao-wei Li, Zhi-hong Ma, Shi-hai Guo, Xin-lin Wang,Structure and electrochemical performances of Mg₂Ni_1−xMn_x(x= 0–0.4) electrode alloys prepared by melt spinning,Electrochimica Acta56 (2010) 427–434

[46]Yang-huan Zhang, Bao-wei Li, Hui-ping Ren, Zhi-hong Ma,Shi-hai Guo,Xin-lin Wang,An electrochemical investigation of melt-spun nanocrystalline Mg₂₀Ni_10-xCu_x(x=0–4) electrode alloys,International Journal of hydrogen energy35(2010 )2385– 2392

[47]Yang-huan Zhang,Bao-wei Li,Hui-ping Ren,Shi-hai Guo,Dong-liang Zhao, Xin-lin Wang,Microstructures and electrochemical performances of La_0.75Mg_0.25Ni_3.5M_x(M = Ni, Co;x= 0–0.6) hydrogen storage alloys,International Journal of Hydrogen Energy35(2010)2040– 2047

[48]Yang-huan Zhang, Rafi-ud-din, Bao-wei Li, Hui-ping Ren, Shi-hai Guo, Xin-lin Wang, Influence of the substituting Ni with Fe on the cycle stabilities of as-cast and as-quenched La_0.7Mg_0.3Co_0.45Ni_2.55−xFe_x(x=0–0.4) electrode alloys,Materials Characterization61(2010) 305–311

[49]Yang-huan Zhang, Shi-hai Guo, Yan Qi, Xia Li, Zhi-hong Ma, Yin Zhang,Enhanced electrochemical characteristics of as-spun nanocrystalline andamorphous Mg₂Ni-type alloy electrodes,Journal of Alloys and Compounds506(2010)749–756

[50] Zhang Yanghuan, Zhao Dongliang, Li Baowei, Qi Yan, Guo Shihai, Wang Xinlin, Hydrogen storage behaviours of nanocrystalline and amorphousMg₂₀Ni_10−xCo_x(x=0-4) alloys prepared by melt spinning,Trans. Nonferrous Met. Soc. China20(3) (2010)405-411

[51]Yang-huan Zhang, Bao-wei Li, Zhi-hong Ma, Shi-hai Guo, Yan Qi, Xin-lin Wang,Improved hydrogen storage behaviours of nanocrystalline and amorphous Mg₂Ni-type alloy by Mn substitution for Ni,International Journal of Hydrogen Energy35(2010)11966–11974

[52]Yang-huan Zhang, Yan Qi, Zhi-hong Ma, Ying Cai, Shi-hai Guo, Xin-lin Wang,Investigation on electrochemical performances of melt-spun nanocrystalline and amorphous Mg₂Ni_1-xMn_x(x =0-0.4) electrode alloys,International Journal of Hydrogen Energy35(2010)11025– 11034

[53]Yang-huan Zhanga, Bao-wei Li, Hui-ping Ren, Shi-hai Guo, Dong-liang Zhao, Xin-lin Wang,Microstructure and hydrogen storage characteristics of melt-spun nanocrystalline Mg₂₀Ni_10−xCu_x(x=0–4) alloys,Materials Chemistry and Physics124(2010)795–802

[54]Zhang Yanghuan, Zhao Dongliang, Li Baowei, Guo Shihai, Qi Yan, Wang Xin-lin, Influence of rapid quenching on hydrogen storage characteristics of nanocrystalline Mg2Ni-type alloys,Trans. Nonferrous Met. Soc. China20(8) (2010)1439-1446

[55]Yang-huan Zhang, Bao-wei Li, Hui-pin Ren, Xiao-xia Ding, Xiao-gang Liu, Le-le Chen,An investigation on hydrogen storage kinetics of nanocrystalline and amorphous Mg₂Ni_1−xCo_x(x= 0–0.4) alloy prepared by melt spinning,Journal of Alloys and Compounds509(2011)2808–2814

[56]Zhang Yanghuan, LuKe, Zhang Dongliang, Guo Shihai, QI Yan, Wang Xinlin,Electrochemical hydrogen storage characteristics of nanocrystalline andamorphous Mg₂Ni-type alloys prepared by melt-spinning,Trans. Nonferrous Met. Soc. China21(3) (2011) 502-511

[57]Yang-Huan Zhang, Bao-Wei Li, Hui-Ping Ren, Xia Li , Yan Qi Dong-Liang Zhao, Enhanced Hydrogen Storage Kinetics of Nanocrystalline and Amorphous Mg₂Ni-type Alloy by Melt Spinning,Materials4(2011)274-287

[58]Yang-huan Zhang, Feng Hu, Zhi-gang Li, Ke Lu, Shi-hai Guo, Xin-lin Wang,Hydrogen storage characteristics of nanocrystalline and amorphous Mg₂Ni-type alloys prepared by melt spinning,Journal of Alloys and Compounds509 (2011) 294–300

[59]Zhang Yanghuan, Song Chunhong, Rren Huiping, Li Zhigang, Hu Feng, Zhao Dongliang,Enhanced hydrogen storage kinetics of nanocrystalline and amorphous Mg₂N-type alloy by substituting Ni with Co,Trans. Nonferrous Met. Soc. China,21(9)( 2011 )2002-2009

[60]Yang-huan Zhang, Bao-wei Li, Hui-ping Ren, Feng Hu, Guo-fang Zhang, Shi-hai Guo,Gaseous and electrochemical hydrogen storage kinetics of nanocrystallineMg₂Ni-type alloy prepared by rapid quenching,Journal of Alloys and Compounds509 (2011) 5604–5610

[61]Zhang Yanghuan, Qi Yan, Zhao Dongliang, Guo Shihai, Ma Zhihong, Wang Xinlin,An investigation of hydrogen storage kinetics of melt-spun nanocrystalline and amorphous Mg₂Ni-type alloys,Journal of Rare Earths,29(1)(2011)87-93

[62]Yang-huan Zhang, Zhong-hui Hou, Bao-wei Li, Hui-ping Ren, Guo-fang Zhang, Dong-liang Zhao,An investigation on electrochemical hydrogen storage performancesof the as-cast and -annealed La_0.8-xSm_xMg_0.2Ni_3.35Al_0.1Si_0.05(x = 0–0.4) alloys,Journal of Alloys and Compounds537(2012)175–182

[63]Yang-huan Zhang, Ying Cai, Chen Zhao, Ting-ting Zhai, Guo-fang Zhang, Dong-liang Zhao,Electrochemical performances of the as-meltLa_0.75-xM_xMg_0.25Ni_3.2Co_0.2Al_0.1(M=Pr, Zr;x=0, 0.2) alloysapplied to Ni/metal hydride (MH) battery,International Journal of Hydrogen Energy37(2012)14590–14597

[64]Yanghuan Zhang, Chen Zhao, Tai Yang, Hongwei Shang, Chao Xu, Dongliang Zhao,Comparative study of electrochemical performances of the as-melt Mg₂₀Ni_10-xM_x(M = None, Cu, Co, Mn;x= 0, 4) alloys applied to Ni/metal hydride (MH) battery,Journal of Alloys and Compounds555 (2013) 131–137

[65]Yanghuan Zhang, Can Li Ying Cai, Feng Hu, Zhuocheng Liu, Shihai Guo,Highly improved electrochemical hydrogen storage performances of the Nd–Cu–added Mg₂Ni-type alloys by melt spinning,Journal of Alloys and Compounds584 (2014) 81–86

[66]Yanghuan Zhang, Haitao Wang, Tingting Zhai, Tai Yang, Yan Qi, Dongliang Zhao,Hydrogen storage characteristics of the nanocrystalline and amorphous Mg-Nd-Ni-Cu based alloys prepared by melt spinning,International Journal of Hydrogen Energy39(2014) 3790-3798

[67]Yang-huan Zhang, Tai Yang, Wen-gang Bu, Ying Cai, Guo-fang Zhang, Dong-liang Zhao, Effect of Nd content on electrochemical performances of nanocrystalline and amorphous (Mg₂₄Ni₁₀Cu₂)_100−xNd_x(x=0−20) alloys prepared by melt spinning,Trans. Nonferrous Met. Soc. China23(2013) 3668−3676

[68] Zhang Yanghuan, Wang Haitao, Yang Tai, Zhai Tingting, Zhang Guofang, Zhao Dongliang,Electrochemical hydrogen storage performances of the nanocrystalline and amorphous (Mg₂₄Ni₁₀Cu₂)_100–xNd_x(x=0–20) alloys applied to Ni-MH battery,Journal of Rare Earth31(12)(2013)1175-1182

[69]Yang-huan Zhang, Hui-ping Ren, Ying Cai, Tai Yang, Guo-fang Zhang, Dong-liang Zhao, Structures and electrochemical hydrogen storage performance of Si added A₂B₇-type alloy electrodes,Trans. Nonferrous Met. Soc. China24(2014) 406−414

[70]Yanghuan Zhang, Tai Yang, Tingting Zhai, Zeming Yuan, Xiaoping Dong, Dongliang Zhao,Hydrogen storage kinetics of as-cast and spun (Mg₂₄Ni₁₀Cu₂)_100-xNd_x(x =0–20) alloy,International Journal of Materials Research105 (12 ) (2014) 1159–1165

[71]Yanghuan Zhang, Tingting Zhai, Baowei Li, Huiping Ren, Wengang Bu, Dongliang Zhao,Highly Improved Gaseous Hydrogen Storage Characteristics of the Nanocrystalline and Amorphous NdeCu-added Mg₂Ni-type Alloys by Melt Spinning,Journal of Materials Science & Technology30(10)(2014)1020-1026

[72]Yanghuan Zhang,Haitao Wang,Xiaoping Dong,Wengang Bu,Zeming Yuan,Guofang Zhang Electrochemical performance of nanocrystalline and amorphous Mg–Nd–Ni–Cu-based Mg₂Ni-type alloy electrodes used in Ni-MH batteries,Acta Metall. Sin. (Engl. Lett.), 27(6)(2014)088–1098

[73]Yang-Huan Zhang, Tai Yang, Hong-Wei Shang,Chen Zhao, Chao Xu, Dong-Liang Zhao, The electrochemical hydrogen storage characteristics of as-spun nanocrystalline and amorphous Mg₂₀Ni_10-xM_x(M=Cu, Co, Mn; x50–4) alloys,Rare Met.33(6) (2014) 663–673

[74]Yang-huan Zhang, Sheng Xu, Ting-ting Zhai, Tai Yang, Ze-ming Yuan, Dong-liang Zhao,Hydrogen storage kinetics of nanocrystalline and amorphous Cu−Nd-added Mg₂Ni-type alloys,Trans. Nonferrous Met. Soc. China24(2014) 3524−3533

[75] Yang-huan Zhang, Peng-xin Li, Tai Yang, Ting-ting Zhai, Ze-ming Yuan, Shi-hai Guo, Effects of substituting La with M (M=Sm, Nd, Pr) on electrochemical hydrogen storage characteristics of A₂B₇-type electrode alloys,Trans. Nonferrous Met. Soc. China24(2014) 4012−4022

[76]Yanghuan Zhang, Zeming Yuan, Tai Yang, Yan Qi , Dongliang Zhao, Effect of mechanical grinding on the electrochemical hydrogen storage properties of Mg–Ni–Yalloy,Journal of Solid State Electrochemistry19(2015)1187–1195

[77]Yanghuan Zhang, Zeming Yuan, Tingting Zhai, Tai Yang, Wengang Bu, Shihai Guo,Effects of Annealing Temperature on the Electrochemical Hydrogen Storage Behaviors of La-Mg-Ni-Based A₂B₇-Type Electrode Alloys,Metallurgical and Materials Transactions A, 46(5)( 2015)2294-2303

[78]Yanghuan Zhang , Zeming Yuan , Tai Yang, Zhonghui Hou, Yan Qi,Electrochemical characteristics of nanocrystalline and amorphous Mg–Y–Ni-based Mg₂Ni-type alloys prepared by mechanical milling,International Journal of Materials Research106(4) (2015) 368 – 377

[79]Yanghuan Zhang,Zeming Yuan,Tai Yang,Yan Qi,Dongliang Zhao,Effect of mechanical grinding on the electrochemical hydrogen storage properties of Mg–Ni–Y alloy,Journal of Solid State Electrochemistry19(2015)1187–1195

[80]Yang-Huan Zhang, Ze-Ming Yuan, Tai Yang, Zhong-Hui Hou, Dong-Liang Zhao,Properties of Mechanically Milled Nanocrystalline and Amorphous Mg–Y–Ni Electrode Alloys for Ni–MH Batteries,Acta Metall. Sin. (Engl. Lett.), 2015, 28(7), 826–836

[81] Yang-Huan Zhang, Sheng-Long Liu, Tai Yang, Guo-Fang Zhang, Xia Li, Dong-Liang Zhao, Gaseous and electrochemical hydrogen storage behaviors of nanocrystalline and amorphous Nd-added Mg₂Ni-type alloys,Rare Met.34(7)( 2015)463–471

[82]Yang-huan Zhang, Tai Yang, Ting-ting Zhai, Ze-ming Yuan, Guo-fang Zhang, Shi-hai Guo, Effects of stoichiometric ratio La/Mg on structures and electrochemical performances of as-cast and annealed La−Mg−Ni-based A₂B₇-type electrode alloys,Trans. Nonferrous Met. Soc. China25(2015) 1968−1977

[83]Yanghuan Zhang,Zeming Yuan, Tingting Zhai,Tai Yang, Guofang Zhang,Electrochemical hydrogen storage behaviors of the nanocrystalline and amorphous Nd-Cu-added Mg₂Ni-type alloy electrodes applied to Ni-MH battery,Journal of Solid State Electrochemistry19(2015)2343–2351

[84]Yanghuan Zhang,Tingting Zhai, Tai Yang, Zeming Yuan, Zhonghui Hou, Yan Qi, Electrochemical hydrogen-storage performance of Mg_20-xY_xNi₁₀(x=0-4) alloys prepared by mechanical milling,Journal of Applied Electrochemistry45 (2015) 931–941

[85]Yanghuan Zhang, Pengjun Zhang, Zeming Yuan, Tai Yang, Yan Qi, Dongliang Zhao,An investigation on electrochemical hydrogen storage performances of Mg-Y-Ni alloys prepared by mechanical milling,Journal of Rare Earths33(8)(2015)874-883

[86]Yang-Huan Zhang, Li-Cui Chen, Tai Yang, Chao Xu, Hui-Ping Ren, Dong-Liang Zhao,The electrochemical hydrogen storage performances of Si-added La–Mg–Ni–Co-based A₂B₇-type electrode alloys,Rare Met.34(8) (2015) 569–579

[87]Yanghuan Zhang, Haitao Wang, Tingting Zhai, Tai Yang, Zeming Yuan, Dongliang Zhao,Hydrogen storage performances of LaMg₁₁Ni +xwt% Ni (x= 100, 200)alloys prepared by mechanical milling,Journal of Alloys and Compounds645 (2015) S438–S445

[88]Yang-huan Zhang, Zhong-gang Han, Ze-ming Yuan, Tai Yang, Yan Qi, Dong-liang Zhao, Electrochemical properties of nanocrystalline and amorphous Mg−Y−Ni alloys applied to Ni-MH battery,Trans. Nonferrous Met. Soc. China25(2015) 3736−3746

[89]Yanghuan Zhang, Baowei Li, Huiping Ren, Tai Yang, Shihai Guo, Yan Qi,Dongliang Zhao,Hydrogenstoragekinetics ofnanocrystalline andamorphousLaMg₁₂-Type Alloy–Nicompositessynthesized bymechanicalmilling,Journal of Materials Science&Technology32 (2016) 218–225

[90] Yanghuan Zhang, Zhichao Jia, Zeming Yuan, Yan Qi, Zhonghui Hou, Dongliang Zhao,Hydrogen storage thermodynamics and kinetics of LaMg₁₁Ni +xwt.% Ni (x= 100, 200) alloys synthesized by mechanical milling,International Journal of Materials Research, 107 (4) (2016)348-355

[91]Yanghuan Zhang,Zeming YuanWengang Bu,Feng Hu, Ying Cai,Dong-Liang Zhao,Hydrogen storage thermodynamics and dynamics of Nd–Mg–Ni-based NdMg₁₂-type alloys synthesized by mechanical milling,Acta Metall. Sin. (Engl. Lett.),29(6)(2016)577–586

[92]Yanghuan Zhang, Zeming Yuan, Tai Yang, Dianchen Feng, Ying Cai, Dongliang Zhao,An investigation on hydrogen storage thermodynamics and kinetics of Pr-Mg-Ni-based PrMg₁₂-type alloys synthesized by mechanical milling,Journal of Alloys and Compounds688 (2016) 585-593

[93]Yanghuan Zhang, Songsong Cui, Xiping Song, PeilongZhang, Yongguo Zhu, Ying Cai, Hydrogen storage kinetics of nanocrystalline and amorphous NdMg₁₂-type alloy–Ni composites synthesized by mechanical milling,International Journal of Materials Research, 107 (7) (2016) 605 – 614

[94]Yanghuan Zhang, Zhonghui Hou, Ying Cai, Feng Hua,, Yan Qi, Dongliang Zhao, Electrochemical hydrogen storage behaviour of as-cast and as-spun RE–Mg–Ni–Mn-based alloys applied to Ni–MH battery,International Journal of Materials Research107(9) (2016)824 – 834

[95]Yanghuan Zhang, Baowei Li, Huiping Ren, Zeming Yuan, Tai Yang, Yan Qi,An investigation on hydrogen storage thermodynamics and kinetics of Nd-Mg-Ni-based alloys synthesized by mechanical milling,International Journal of Hydrogen Energy41(2016)12205-12213

[96]Yanghuan Zhang, Hongwei Shang, Zhonghui Hou, Zeming Yuan, Tai Yang, and Yan Qi,Hydrogen storage characteristics of nanocrystalline and amorphous Nd-Mg-Ni-based NdMg₁₂-type alloys synthesizedviamechanical milling,Metallurgical and Materials Transactions A47(12) (2016)6404-6412

[97]Yanghuan Zhang, Tai Yang, Ying Cai, Feng Hu, Yan Qi, Dongliang Zhao,Structures and electrochemical performances of RE-Mg-Ni-Mn-based alloys prepared by casting and melt spinning,Journal of Rare Earths34(12)(2016)1241-1251

[98]Yanghuan Zhang, Yaqin Li, Hongwei Shang, Zeming Yuan, Tai Yang, Shi-hai Guo, Structures and hydrogen storage performances of rare earth-Mg-Ni-Mn-based AB₂-type alloys applied to Ni-MH battery,Journal of Solid State Electrochemistry21(2017)1015–1025

[99]Yanghuan Zhang, Dianchen Feng, Hao Sun, Wengang Bu, Yan Qi, Shihai Guo,Structure and electrochemical hydrogen storage characteristics of Ce-Mg-Ni-based alloys synthesized by mechanical milling,Journal of Rare Earths35(3)(2017)280-289

[100]Yanghuan Zhang, Zeming Yuan, Hongwei Shang, Yaqin Li, Yan Qi, and Dongliang Zhao,Structures and electrochemical hydrogen storage properties of the as-spun RE-Mg-Ni-Co-Al-based AB₂-type alloys applied to Ni-MH battery,Metallurgical and Materials Transactions A48(5)(2017)2472-2482

[101]Yanghuan Zhang,Yaqin Li,Hongwei Shang,ZemingYuan,Yan Qi,DongliangZhao.Hydrogen storage performances of the as-milled REMg₁₁Ni (RE = Sm, Y) alloys catalyzed by CeO₂Progress in Natural Science: Materials International28(2018)259-265

[102]Yanghuan Zhang,Songsong Cui,ZemingYuan,Jinliang Gao, Xiaoping Dong, Yan Qi, Shihai Guo. Hydrogen Storage Performances of REMg₁₁Ni (RE = Sm, Y) Alloys Prepared by Mechanical Milling,Metallurgical and Materials Transactions A49(2018)376-384

[103]Yanghuan Zhang, Songsong Cuia, Yaqin Li, Hongwei Shang, Yan Qi, Dongliang Zhao,Structures and electrochemical performances of as-spun RE-Mg-Ni-Co-Al alloys applied to Ni-MH battery,Journal of Materials Science&Technology34(2018)370-378

[104]Yanghuan Zhang,Yaqin Li,Hongwei Shang,ZemingYuan,Yan Qi,DongliangZhao, Shihai Guo,Hydrogen storage performance of the as-milled Y-Mg-Ni alloy catalyzed by CeO₂International Journal of Hydrogen Energy43(2018)1643-1650

[105]Yanghuan Zhang, Meng Ji, Zeming Yuan, Jingliang Gao, Yan Qi, Xiaoping Dong , Shihai Guo, A comparison study of hydrogen storage performances of SmMg₁₁Ni alloys prepared by melt spinning and ball milling,Journal of Rare Earths36 (2018)409-417

[106]Yanghuan Zhang,Yaqin Li,Hongwei Shang,Zhong-hui Hou, Yan Qi, Dong-liang Zhao, Electrochemical hydrogen storage performance of as-cast and as-spun RE−Mg−Ni−Co−Al-based alloys applied to Ni/MH battery,Trans. Nonferrous Met. Soc. China28(2018) 711-721

出版专著：

1.Zhang Yanghuan，Wang Xinlin，Preparation Technologies and Electrochemical Properties of Hydrogen Storage Alloys，Metallurgical Industry Press，748000，2008.3.1

2.Zhang Yanghuan，The Preparation and Hydrogen Storage Performances of Nanocrystalline and Amorphous Mg₂Ni-Type Alloys，InTech, Chapter4 published，13000，2012.9.5

3.Zhang Yanghuan，The Preparation and Electrochemical Hydrogen Storage Characteristics of AB₃- and A₂B₇-type Alloys，New York: Nova Science Publishers，9500，2013.01.01

授权发明专利

1. 张羊换，赵栋梁，王新林，李平，庞在广，一种高容量Mg₂Ni型贮氢合金非晶带材及其制备方法，中国，ZL200710117709.X

2. 张羊换，尚宏伟，李龙文，赵栋梁，祁焱，郭世海，一种风电储能用稀土-钛铁储氢合金，中国，ZL201510623781.4

3. 张羊换，胡锋，冯佃臣，CoS2催化的高容量贮氢合金及其制备方法，中国，ZL201410040862.7

4. 张羊换，任慧平，张胤，张国芳，李霞，MoS2催化的高容量贮氢合金及其制备方法，中国，ZL201310655319.3

5. 张羊换，任慧平，张胤，侯忠辉，胡锋，Ni-MH电池用高容量贮氢电极合金及其制备方法，中国，ZL201310673518.7

6. 张羊换，张国芳，侯忠辉，胡锋，刘卓承，李霞，一种Mg-Ti-RE-Ni基贮氢合金及其制备方法，中国，ZL201510041073.X

7. 张胤，张羊换，李霞，侯忠辉，胡锋，张国芳，一种纳米CeO2催化的高容量RE-Mg-Ni基贮氢合金及其制备方法，中国，ZL201310627394.9

8. 任慧平，张羊换，张胤，刘卓成，胡锋，纳米晶-非晶高容量贮氢电极合金及其制备方法，中国，ZL201310651533.1

   9.赵增武，任慧平，张羊换，高容量贮氢电极合金及其制备方法，中国，ZL201410087294.6

   10林玉芳，赵栋梁，张羊换，赵海花，李平，董小平，RE-Mg-Ni型金属氢化物二次电池用储氢合金及其制备方法，中国，ZL200910089697.3